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What is Molybdenum?
Molybdenum (Mo) is a refractory metallic element used principally as an alloying agent in
steel, cast iron, and superalloys to enhance hardenability, strength, toughness,
and wear and corrosion resistance. To achieve desired metallurgical properties,
molybdenum, primarily in the form of molybdic oxide or ferromolybdenum, is
frequently used in combination with or added to chromium, columbium (niobium),
manganese, nickel, tungsten, or other alloy metals. The versatility of
molybdenum in enhancing a variety of alloy properties has ensured it a
significant role in contemporary industrial technology, which increasingly
requires materials that are serviceable under high stress, expanded temperature
ranges, and highly corrosive environments. Moreover, molybdenum finds
significant usage as a refractory metal in numerous chemical applications,
including catalysts, lubricants, and pigments. Few of molybdenum's uses have
acceptable substitutions.
Reserves
Molybdenum is only known to occur in a natural state chemically combined with
other elements. Although a number of molybdenum-bearing minerals have been
identified, the only one of commercial significance is molybdenite (MoS2) - a
natural molybdenum sulphide. In ore bodies, molybdenite is generally present in
quantities from 0.01- 0.50% and is often associated with the sulphide minerals
of other metals, notably copper.
Reserves are mainly located in the western mountain regions of North and South
America.
The USA is by far the largest producing country, and also has the largest
reserve base of 5.4 million tonnes, nearly half of the world's total.
History
Molybdenum was not discovered until the latter part of the 18th century, and
does not occur in the metallic form in nature. Despite this, its predominant
mineral - molybdenite - was surely utilised in ancient times but would have been
indistinguishable from other similar materials such as lead, galena and
graphite. Collectively, these substances were known by the Greek word "molybdos",
which means lead-like.
A 14th century Japanese sword has been found to contain molybdenum. However, it
was not until 1778 that the Swedish scientist, Carl Wilhelm Scheele, was able
positively to identify molybdenum. He decomposed molybdenite by heating it in
air to yield a white oxide powder. Shortly thereafter, in 1782, Peter Jacob
Hjelm reduced the oxide with carbon to obtain a dark metallic powder which he
named "molybdenum".
Molybdenum remained mainly a laboratory curiosity throughout most of the 19th
century until the technology for the extraction of commercial quantities became
practical. In 1891, the French company Schneider & Co. first used molybdenum as
an alloying element in the production of armour plate. It was quickly noted
that, with a density of only slightly more than half that of tungsten,
molybdenum was an effective replacement for tungsten in numerous steel alloying
applications.
World War I caused tungsten demand to soar and severely strained its supply. As
a direct result, molybdenum was substituted for tungsten in many hard and impact
resistant steels. The resulting increased demand initiated an intensive search
for new sources of molybdenum supply, culminating with the development of the
massive Climax deposit in Colorado, USA and its initial operation in 1918.
The end of the war and the consequent reductions in demand triggered research
efforts to develop new civilian applications for molybdenum. A number of new
low-alloy molybdenum automotive steels were soon tested and accepted. The big
breakthrough however, occurred in the 1930's with the determination of proper
temperature ranges for the forging and heat treatment of molybdenum-bearing
high-speed steels. From this beginning, research eventually developed a full
understanding of how molybdenum imparts its many cost-effective benefits as an
alloying element to steels and other systems.
By the end of the 1930's, molybdenum was a widely accepted technical material.
The conclusion of World War II in 1945 once again brought increased research
investment to develop new civilian applications, and the post-war reconstruction
of the world provided additional markets for structural steels, many of which
already contained some molybdenum.
The years from 1945 to the present have seen a dramatically expanding range of
applications for molybdenum, its alloys and its compounds. Rising demand has
been comfortably balanced by new sources of assured supply and by new processing
technologies with superior recovery rates.
Although steels and cast iron comprise the single biggest market segment,
molybdenum's diversity has also proven invaluable in superalloys, nickel base
alloys, lubricants, chemicals, electronics and many other applications. |